A new approach to nickel electrolytic colouring of anodised aluminium

Zemanová, Matilda, Chovancová, Marta and Krivošík, Pavol A new approach to nickel electrolytic colouring of anodised aluminium Chemical Papers, Vol.63, No. 1, 2009, 62-70

Document type: Článok z časopisu / Journal Article
Collection: Chemical papers  

Author(s) Zemanová, Matilda
Chovancová, Marta
Krivošík, Pavol
Title A new approach to nickel electrolytic colouring of anodised aluminium
Journal name Chemical Papers
Publication date 2009
Year available 2009
Volume number 63
Issue number 1
ISSN 0366-6352
Start page 62
End page 70
Place of publication Poland
Publisher Versita
Collection year 2009
Language english
Subject 250000 Chemical Sciences
250200 Inorganic Chemistry
Abstract/Summary Energy dispersive X-ray spectroscopy and scanning electron microscopy were used to analyse nickel on anodic aluminium surfaces after stripping the anodic aluminium oxide. The metal was electroplated at the bottom of the pores of anodised aluminium during electrolytic colouring in solutions without (Watts) and with (citrate) complexing agents, respectively. A relation between the anodic-cathodic processes, changes of the structure and composition of the coating in dependence on the used solution were studied. A morphology study performed after stripping the anodic aluminium oxide revealed the crucial influence of the anodic process/cycle and the complexing agent on the nickel structure on the aluminium surface. Off-time of half-way rectified current influenced the nickel deposition in the pores of anodic alumina negatively.
 
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