Determination of the enthalpy of fusion of K3TaO2F4 and KTaF6

Kosa, Ladislav, Macková, Iveta and Netriová, Zuzana Determination of the enthalpy of fusion of K3TaO2F4 and KTaF6 Chemical Papers, Vol.63, No. 4, 2009, 493-496

Document type: Článok z časopisu / Journal Article
Collection: Chemical papers  

Author(s) Kosa, Ladislav
Macková, Iveta
Netriová, Zuzana
Title Determination of the enthalpy of fusion of K3TaO2F4 and KTaF6
Journal name Chemical Papers
Publication date 2009
Year available 2009
Volume number 63
Issue number 4
ISSN 0366-6352
Start page 493
End page 496
Place of publication Poland
Publisher Versita
Collection year 2009
Language english
Subject 250000 Chemical Sciences
250200 Inorganic Chemistry
Abstract/Summary Areas of fusion and crystallization peaks of K3TaO2F4 and KTaF6 were measured using the DSC mode of a high-temperature calorimeter (SETARAM 1800 K). On the basis of these quantities, considering the temperature dependence of the calorimeter sensitivity, values of the fusion enthalpy of K3TaO2F4 at the fusion temperature of 1181 K of (43 ± 4) kJ mol−1 and of KTaF6 at the fusion temperature of 760 K of (8 ± 1) kJ mol−1 were determined.
 
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