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Gas chromatography with ballistic heating and ultrafast cooling of column
Krkošová, Žofia, Kubinec, Róbert, Jurdáková, Helena, Blaško, Jaroslav, Ostrovský, Ivan, Soják, Ladislav and Ševčík, Jiří Gas chromatography with ballistic heating and ultrafast cooling of column Chemical Papers, Vol.62, No. 2, 2008, 135-140
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Document type:
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Článok z časopisu / Journal Article |
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Collection:
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Chemical papers
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| Author(s) |
Krkošová, Žofia
Kubinec, Róbert
Jurdáková, Helena
Blaško, Jaroslav
Ostrovský, Ivan
Soják, Ladislav
Ševčík, Jiří
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| Title |
Gas chromatography with ballistic heating and ultrafast cooling of column
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| Journal name |
Chemical Papers
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| Publication date |
2008
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| Year available |
2008
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| Volume number |
62
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| Issue number |
2
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| ISSN |
0366-6352
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| Start page |
135
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| End page |
140
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| Place of publication |
Poland
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| Publisher |
Versita
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| Collection year |
2008
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| Language |
english
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| Subject |
250000 Chemical Sciences
250400 Analytical Chemistry
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| Abstract/Summary |
An overview of the existing methods for minimization of the analysis time in gas chromatography (GC) is presented and a new system for fast temperature programming and very fast cooling down is evaluated. In this study, a system of coaxial tubes, a heating/cooling module (HC-M), was developed and studied with a capillary column placed inside the HC-M. The module itself was heated by a GC oven and cooled down by an external cooling medium. The HC-M was heated at rates of up to 330 °C min−1 and cooled at the rate of 6000 °C min−1. The GC system was prepared for the next run within a few seconds. The HC-M permits good separation reproducibility, comparable with that of a conventional GC, expressed in terms of relative retention times and peak areas of analytes reproducibilities. The HC-M can be used within any commercial gas chromatograph.
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