Interaction of Aminooxyalkylphosphonic Acids with Cobalt(II), Nickel(II), and Copper(II)

Kucharska-Zoń, M., Zoń, J. and Wojciechowski, W. Interaction of Aminooxyalkylphosphonic Acids with Cobalt(II), Nickel(II), and Copper(II) Chemical Papers, Vol.56, No. 2, 2002, 89-94

Document type: Článok z časopisu / Journal Article
Collection: Chemical papers  

Author(s) Kucharska-Zoń, M.
Zoń, J.
Wojciechowski, W.
Title Interaction of Aminooxyalkylphosphonic Acids with Cobalt(II), Nickel(II), and Copper(II)
Journal name Chemical Papers
Publication date 2002
Year available 2002
Volume number 56
Issue number 2
ISSN 0366-6352
Start page 89
End page 94
Place of publication Poland
Publisher Versita
Collection year 2002
Language english
Subject 250000 Chemical Sciences
250200 Inorganic Chemistry
Abstract/Summary The series of new complexes with perchlorate cobalt(II), nickel(II), copper(II), and aminooxyalkylphosphonic acids have been synthesized in polycrystalline form. They are first synthesized complexes with aminooxyalkylphosphonic acids. The structures were proposed based on spectroscopic data (IR, UV VIS, FIR, EPR) and the measured magnetic moments. The oxygen atom of the aminooxy group takes part in coordination with metal ion in aminooxymethylphosphonic acid but it does not coordinate in 1-aminooxyethylphosphonic acid and 2-aminooxyethylphosphonic acid. The weaker binding ability of the aminooxy group oxygen atom could be attributed to geometry of the ligands.
 
 
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Created: Mon, 04 Jan 2010, 09:21:19 CET by Jana Taptičová . Detailed History