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Interaction of Aminooxyalkylphosphonic Acids with Cobalt(II), Nickel(II), and Copper(II)
Kucharska-Zoń, M., Zoń, J. and Wojciechowski, W. Interaction of Aminooxyalkylphosphonic Acids with Cobalt(II), Nickel(II), and Copper(II) Chemical Papers, Vol.56, No. 2, 2002, 89-94
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Document type:
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Článok z časopisu / Journal Article |
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Collection:
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Chemical papers
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| Author(s) |
Kucharska-Zoń, M.
Zoń, J.
Wojciechowski, W.
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| Title |
Interaction of Aminooxyalkylphosphonic Acids with Cobalt(II), Nickel(II), and Copper(II)
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| Journal name |
Chemical Papers
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| Publication date |
2002
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| Year available |
2002
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| Volume number |
56
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| Issue number |
2
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| ISSN |
0366-6352
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| Start page |
89
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| End page |
94
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| Place of publication |
Poland
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| Publisher |
Versita
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| Collection year |
2002
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| Language |
english
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| Subject |
250000 Chemical Sciences
250200 Inorganic Chemistry
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| Abstract/Summary |
The series of new complexes with perchlorate cobalt(II), nickel(II), copper(II), and aminooxyalkylphosphonic acids have been synthesized in polycrystalline form. They are first synthesized complexes with aminooxyalkylphosphonic acids. The structures were proposed based on spectroscopic data (IR, UV VIS, FIR, EPR) and the measured magnetic moments. The oxygen atom of the aminooxy group takes part in coordination with metal ion in aminooxymethylphosphonic acid but it does not coordinate in 1-aminooxyethylphosphonic acid and 2-aminooxyethylphosphonic acid. The weaker binding ability of the aminooxy group oxygen atom could be attributed to geometry of the ligands.
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