Preparation, Spectral and Thermal Properties of Dicyanoargentates of Copper and Nickel with Bipyridine

Chomič, J., Černák, J. and Bálintová, M. Preparation, Spectral and Thermal Properties of Dicyanoargentates of Copper and Nickel with Bipyridine Chemical Papers, Vol.56, No. 2, 2002, 84-88

Document type: Článok z časopisu / Journal Article
Collection: Chemical papers  

Author(s) Chomič, J.
Černák, J.
Bálintová, M.
Title Preparation, Spectral and Thermal Properties of Dicyanoargentates of Copper and Nickel with Bipyridine
Journal name Chemical Papers
Publication date 2002
Year available 2002
Volume number 56
Issue number 2
ISSN 0366-6352
Start page 84
End page 88
Place of publication Poland
Publisher Versita
Collection year 2002
Language english
Subject 250000 Chemical Sciences
250200 Inorganic Chemistry
Abstract/Summary Coordination compounds [Ni(bipy)3]2[Ag(CN)2]3Cl · 9H2O (NB3AH), [Ni(bipy)2][Ag(CN)2]2 · H2O (NB2AH), and [Cu(bipy)2][Ag(CN)2]2 ·H2O (CB2AH), respectively, have been prepared and identified by elemental analysis, infrared and electron spectroscopy. Thermal stability and stoichiometry of thermal decomposition were studied by using a derivatograph. The intermediates of thermal decomposition were identified by IR spectroscopy and X-ray powder diffractometry. The results indicate that the thermal stability increases in the order NB3AH, CB2AH, NB2AH.
 
 
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Created: Mon, 04 Jan 2010, 09:19:35 CET by Jana Taptičová . Detailed History