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Preparation, Spectral and Thermal Properties of Dicyanoargentates of Copper and Nickel with Bipyridine
Chomič, J., Černák, J. and Bálintová, M. Preparation, Spectral and Thermal Properties of Dicyanoargentates of Copper and Nickel with Bipyridine Chemical Papers, Vol.56, No. 2, 2002, 84-88
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Document type:
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Článok z časopisu / Journal Article |
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Collection:
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Chemical papers
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| Author(s) |
Chomič, J.
Černák, J.
Bálintová, M.
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| Title |
Preparation, Spectral and Thermal Properties of Dicyanoargentates of Copper and Nickel with Bipyridine
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| Journal name |
Chemical Papers
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| Publication date |
2002
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| Year available |
2002
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| Volume number |
56
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| Issue number |
2
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| ISSN |
0366-6352
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| Start page |
84
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| End page |
88
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| Place of publication |
Poland
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| Publisher |
Versita
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| Collection year |
2002
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| Language |
english
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| Subject |
250000 Chemical Sciences
250200 Inorganic Chemistry
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| Abstract/Summary |
Coordination compounds [Ni(bipy)3]2[Ag(CN)2]3Cl · 9H2O (NB3AH), [Ni(bipy)2][Ag(CN)2]2 · H2O (NB2AH), and [Cu(bipy)2][Ag(CN)2]2 ·H2O (CB2AH), respectively, have been prepared and identified by elemental analysis, infrared and electron spectroscopy. Thermal stability and stoichiometry of thermal decomposition were studied by using a derivatograph. The intermediates of thermal decomposition were identified by IR spectroscopy and X-ray powder diffractometry. The results indicate that the thermal stability increases in the order NB3AH, CB2AH, NB2AH.
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