Phase Diagram and Structure of Melts of the System CaO—TiO2—SiO2

Daněk, V. and Nerád, I. Phase Diagram and Structure of Melts of the System CaO—TiO2—SiO2 Chemical Papers, Vol.56, No. 4, 2002, 241-246

Document type: Článok z časopisu / Journal Article
Collection: Chemical papers  
 
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Author(s) Daněk, V.
Nerád, I.
Title Phase Diagram and Structure of Melts of the System CaO—TiO2—SiO2
Journal name Chemical Papers
Publication date 2002
Year available 2002
Volume number 56
Issue number 4
ISSN 0366-6352
Start page 241
End page 246
Place of publication Poland
Publisher Versita
Collection year 2002
Language english
Subject 250000 Chemical Sciences
250200 Inorganic Chemistry
Abstract/Summary Phase diagrams of the systems CaO—TiO2 and CaO—TiO2—SiO2 were calculated using thermodynamic model of silicate melts. The calculated phase diagrams fit the experimentally determined ones well, assuming that the present TiO2 behaves as network-forming oxide in the prevailing concentration region of the ternary system. For the better fit in the CaO-, TiO2-, and SiO2-rich concentration regions, the activities of these components were set to be equal to their mole fraction. This means that in the prevailing concentration region of the ternary system TiO2 participates in the formation of the polyanionic network.
 
 
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