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Bis(5-Me(O)salicylato)copper(II) Complexes with/without Diethylnicotinamide - Preparation, Structure and Properties
Repická, Zuzana, Krupková, Lenka, Korabik, Maria, Moncoľ, Ján, Hudecová, Daniela and Valigura, Dušan Bis(5-Me(O)salicylato)copper(II) Complexes with/without Diethylnicotinamide - Preparation, Structure and Properties Acta Chimica Slovaca, Vol.2, No. 2, 2009, 52-62
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| Attached Files |
| Name |
Description |
MIMEType |
Size |
Downloads |
acs_0046.pdf
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acs_0046.pdf |
application/pdf |
201.82KB |
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| Author(s) |
Repická, Zuzana
Krupková, Lenka
Korabik, Maria
Moncoľ, Ján
Hudecová, Daniela
Valigura, Dušan
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| Title |
Bis(5-Me(O)salicylato)copper(II) Complexes with/without Diethylnicotinamide - Preparation, Structure and Properties
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| Journal name |
Acta Chimica Slovaca
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| Publication date |
2009
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| Year available |
2009
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| Volume number |
2
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| Issue number |
2
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| ISSN |
1337-978X
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| Start page |
52
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| End page |
62
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| Total pages |
11
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| Place of publication |
Bratislava
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| Publisher |
Slovak Technical University
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| Collection year |
2009
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| Language |
english
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| Subject |
250000 Chemical Sciences
250200 Inorganic Chemistry
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| Abstract/Summary |
Monomeric [Cu(5-Me(O)sal)2(denia)2(H2O)2] and polymeric [Cu(5-Me(O)sal)2(denia)(H2O)]n complexes (where 5-Me(O)sal = 5-methyl- or 5-methoxysalicylato anion and denia = N,Ndiethylnicotinamide) have been prepared and studied together with the pair of complexes without diethylnicotinamide – [Cu(5-Me(O)sal)2(H2O)2]. The composition of all complexes has been determined by elemental analysis and their ligand coordination modes and stereochemistry have been determined by electronic, infrared and EPR spectroscopy, and for some of them their structures have been solved, and for [Cu(5-MeOsal)2(denia)(H2O)]n the magnetic properties were analyzed too. The complexes have been evaluated for their antimicrobial activities against selected bacteria, yeasts and fungi strains.
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| Keyword(s) |
copper complexes
salicylato ligand
diethylnicotinamide
crystal structure
antimicrobial activity
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