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Synthesis, structure, and solvent-extraction properties of tridentate oxime ligands and their cobalt(II), nickel(II), copper(II), zinc(II) complexes
Dede, Bülent, Karipcin, Fatma, Arabalı, Filiz and Cengiz, Mustafa Synthesis, structure, and solvent-extraction properties of tridentate oxime ligands and their cobalt(II), nickel(II), copper(II), zinc(II) complexes Chemical Papers, Vol.64, No. 1, 2010, 25-33
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Document type:
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Článok z časopisu / Journal Article |
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Collection:
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Chemical papers
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| Author(s) |
Dede, Bülent
Karipcin, Fatma
Arabalı, Filiz
Cengiz, Mustafa
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| Title |
Synthesis, structure, and solvent-extraction properties of tridentate oxime ligands and their cobalt(II), nickel(II), copper(II), zinc(II) complexes
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| Journal name |
Chemical Papers
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| Publication date |
2010
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| Year available |
2010
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| Volume number |
64
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| Issue number |
1
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| ISSN |
0366-6352
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| Start page |
25
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| End page |
33
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| Place of publication |
Poland
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| Publisher |
Versita
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| Collection year |
2010
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| Language |
english
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| Subject |
250000 Chemical Sciences
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| Abstract/Summary |
Synthesis of four different types of ligands Ar[COC(NOH)R] n (Ar = biphenyl, n = 1, HL1; Ar = biphenyl, n = 2, H2L2; Ar = diphenylmethane, n = 1, HL3; Ar = diphenylmethane, n = 2, H2L4; R = furfurylamine in all ligands) and their dinuclear Co2+, Ni2+, Cu2+, and Zn2+ complexes is reported herein. These compounds were characterized by elemental analysis, ICP-OES, FT-IR spectra, and magnetic susceptibility measurements. The ligands were further characterized by 1H NMR. The results suggest that dinuclear complexes of HL1 and HL3 have a metal to ligand mole ratio of 2: 2 and dinuclear complexes H2L2 and H2L4 have a metal to ligand mole ratio of 2: 1. Square pyramidal or octahedral structures are proposed for complexes of oxime ligands. Furthermore, extraction abilities of the four ligands were also evaluated in chloroform using selected transition metal picrates such as Mn2+, Co2+, Ni2+, Cu2+, Zn2+, Cd2+, Hg2+, Pb2+. The ligands show strong binding ability towards Hg2+ and Cu2+ ions.
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