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Reactivation of a palladium catalyst during glucose oxidation by molecular oxygen
Gogová, Zuzana and Hanika, Jiří Reactivation of a palladium catalyst during glucose oxidation by molecular oxygen Chemical Papers, Vol.63, No. 5, 2009, 520-526
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Document type:
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Článok z časopisu / Journal Article |
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Collection:
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Chemical papers
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| Author(s) |
Gogová, Zuzana
Hanika, Jiří
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| Title |
Reactivation of a palladium catalyst during glucose oxidation by molecular oxygen
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| Journal name |
Chemical Papers
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| Publication date |
2009
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| Year available |
2009
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| Volume number |
63
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| Issue number |
5
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| ISSN |
0366-6352
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| Start page |
520
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| End page |
526
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| Place of publication |
Poland
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| Publisher |
Versita
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| Collection year |
2009
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| Language |
english
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| Subject |
290000 Engineering and Technology
290600 Chemical Engineering
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| Abstract/Summary |
Kinetic data of glucose oxidation in aqueous solution catalyzed by heterogeneous palladium catalyst are presented under conditions of the catalyst reversible deactivation by oxygen. Measurements were run in a semi-continuous stirred tank reactor at 30°C and atmospheric pressure in kinetic regime. Effect of the reaction mixture composition on the reaction rate is presented. The catalyst activation/reactivation technique is discussed and optimized. Relation between optimal activation time and glucose concentration was defined.
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