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A strategy for new macrocycle magnetic materials synthesis
Mroziński, Jerzy and Alina Bieńko A strategy for new macrocycle magnetic materials synthesis Chemical Papers, Vol.63, No. 3, 2009, 306-312
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Document type:
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Článok z časopisu / Journal Article |
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Collection:
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Chemical papers
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| Author(s) |
Mroziński, Jerzy
Alina Bieńko
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| Title |
A strategy for new macrocycle magnetic materials synthesis
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| Journal name |
Chemical Papers
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| Publication date |
2009
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| Year available |
2009
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| Volume number |
63
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| Issue number |
3
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| ISSN |
0366-6352
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| Start page |
306
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| End page |
312
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| Place of publication |
Poland
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| Publisher |
Versita
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| Collection year |
2009
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| Language |
english
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| Subject |
250000 Chemical Sciences
250500 Macromolecular Chemistry
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| Abstract/Summary |
A study of a series of new types of copper(II) and rhenium(IV) macrocyclic complexes, important macrocyclic molecular magnets, is reported. A detailed description of crystal structure and magnetic behavior of mononuclear copper(II) macrocyclic compounds: CuL1(ClO4)2 (L1 = N-d-2,4,4,9,11,11-hexamethyl-1,5,8,12-tetraazacyclotetradeca-2,9-diene), CuL2(ClO4)2 (L2 = N-d-7,14-diisopropyl-5,12-dimethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene) and of heteropolynuclear complexes: [CuL1][ReCl4(ox)] · DMF and [(CuL2)(ox)ReCl4] is presented. The results indicate that all compounds behave as weak interacting magnets.
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