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Mild and efficient conversion of trifluoromethylarenes into tribromomethylarenes using boron tribromide
Chen, Hongbiao, Yin, Jianxiang and Lin, Yuanbin Mild and efficient conversion of trifluoromethylarenes into tribromomethylarenes using boron tribromide Chemical Papers, Vol.63, No. 1, 2009, 92-96
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Document type:
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Článok z časopisu / Journal Article |
Collection:
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Chemical papers
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Author(s) |
Chen, Hongbiao Yin, Jianxiang Lin, Yuanbin
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Title |
Mild and efficient conversion of trifluoromethylarenes into tribromomethylarenes using boron tribromide
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Journal name |
Chemical Papers
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Publication date |
2009
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Year available |
2009
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Volume number |
63
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Issue number |
1
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ISSN |
0366-6352
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Start page |
92
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End page |
96
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Place of publication |
Poland
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Publisher |
Versita
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Collection year |
2009
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Language |
english
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Subject |
250000 Chemical Sciences
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Abstract/Summary |
Tribromomethylarenes were prepared efficiently, at room temperature, from trifluoromethylarenes with boron tribromide as the brominating reagent. The present process is applicable to the preparation of various substituted benzotribromide derivatives from substituted benzotrifluoride compounds. p-Substituted benzotrifluoride compounds were found to be more reactive than o-substituted isomers under the given reaction conditions.
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