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Synthesis of macrocyclic polyethers and polyether diesters and preparation of their cationic complexes
Ertul, Şeref, Bedük, A. Dinçer, Bayrakci, Mevlüt and Güler, Ersin Synthesis of macrocyclic polyethers and polyether diesters and preparation of their cationic complexes Chemical Papers, Vol.62, No. 6, 2008, 589-595
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Document type:
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Článok z časopisu / Journal Article |
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Collection:
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Chemical papers
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| Author(s) |
Ertul, Şeref
Bedük, A. Dinçer
Bayrakci, Mevlüt
Güler, Ersin
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| Title |
Synthesis of macrocyclic polyethers and polyether diesters and preparation of their cationic complexes
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| Journal name |
Chemical Papers
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| Publication date |
2008
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| Year available |
2008
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| Volume number |
62
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| Issue number |
6
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| ISSN |
0366-6352
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| Start page |
589
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| End page |
595
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| Place of publication |
Poland
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| Publisher |
Versita
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| Collection year |
2008
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| Language |
english
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| Subject |
250000 Chemical Sciences
250500 Macromolecular Chemistry
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| Abstract/Summary |
New macrocyclic polyethers, 2,3,5,6-bis-[5′(5′)-chlorobenzo]-1,7,10-trioxacyclododeca-2,5-diene (I), 2,3,5,6-bis-[5′(5′)-chlorobenzo]-1,7,10,13-tetra oxacyclo pentadeca-2,5-diene (II), and 2,3,5,6-bis-[5′(5′)-chlorobenzo]-1,7,10,13,16-penta oxa cyclo octadeca-2,5-dien (III), and macrocylic lactones 2,3,5,6-bis-[5′(5′)-chlorobenzo]-1,7,10,13-tetraoxacyclopentadeca-2,5-diene-8,15-dione (IV) and 2,3,5,6-bis[5′(5′)-chlorobenzo]-1,7,10,13,16-pentaoxacyclooctadeca-2,5-diene-8,18-dione (V) were synthesized. Complexes of ligands III and V with metal cations were prepared. Furthermore, their metal-picrate extraction with some metal salts was attempted. Structures of the ligands and complexes were confirmed using spectroscopic techniques.
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