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Palladium-catalyzed heck and suzuki coupling in glycerol
Wolfson, A. and Dlugy, C. Palladium-catalyzed heck and suzuki coupling in glycerol Chemical Papers, Vol.61, No. 3, 2007, 228-232
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Document type:
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Článok z časopisu / Journal Article |
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Collection:
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Chemical papers
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| Author(s) |
Wolfson, A.
Dlugy, C.
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| Title |
Palladium-catalyzed heck and suzuki coupling in glycerol
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| Journal name |
Chemical Papers
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| Publication date |
2007
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| Year available |
2007
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| Volume number |
61
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| Issue number |
3
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| ISSN |
0366-6352
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| Start page |
228
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| End page |
232
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| Place of publication |
Poland
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| Publisher |
Versita
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| Collection year |
2007
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| Language |
english
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| Subject |
290000 Engineering and Technology
290600 Chemical Engineering
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| Abstract/Summary |
The Heck coupling of halobenzenes with various alkenes and the Suzuki cross coupling of halobenzenes with phenylboronic acid were successfully performed in glycerol as the reaction solvent using homogeneous and heterogeneous palladium catalysts. Glycerol is a renewable and recyclable green solvent that is able to dissolve organic substrates, inorganic bases, and palladium complexes, and that allows easy isolation of the reaction product by simple extraction with glycerol-immiscible solvents such as diethyl ether, hexane, and dichloromethane.
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