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Thermally stable oligomer—Metal complexes based on oligo-ortho-aminophenol and oligophenylazomethinephenol
Mart, H., Koç, M. C., Muradoğlu, V. and Yürük, H. Thermally stable oligomer—Metal complexes based on oligo-ortho-aminophenol and oligophenylazomethinephenol Chemical Papers, Vol.60, No. 4, 2006, 306-310
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Document type:
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Článok z časopisu / Journal Article |
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Collection:
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Chemical papers
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| Author(s) |
Mart, H.
Koç, M. C.
Muradoğlu, V.
Yürük, H.
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| Title |
Thermally stable oligomer—Metal complexes based on oligo-ortho-aminophenol and oligophenylazomethinephenol
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| Journal name |
Chemical Papers
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| Publication date |
2006
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| Year available |
2006
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| Volume number |
60
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| Issue number |
4
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| ISSN |
0366-6352
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| Start page |
306
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| End page |
310
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| Place of publication |
Poland
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| Publisher |
Versita
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| Collection year |
2006
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| Language |
english
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| Subject |
250000 Chemical Sciences
250500 Macromolecular Chemistry
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| Abstract/Summary |
The oligo-ortho-aminophenol was synthesized by the oxidative polycondensation of ortho-aminophenol with air oxygen. The oligophenylazomethinephenol was synthesized by the condensation of aniline with oligosalicylaldehyde. Metal complexes of these oligomers with Cu(II), Co(II), Zn(II), and Ni(II) were synthesized and characterized. Based on the results of thermogravimetric analysis, synthesized oligomer—metal complexes were more stable against heat and thermooxidative decomposition than some polymeric Schiff bases and polymer—metal complexes. Additionally, the presence of metal ions increased the thermal stability of oligo-ortho-aminophenol, while the thermal stability of oligophenylazomethinephenol was lowered.
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