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Complexes of biologically important ligands. I. Ternary complexes of nickel(II) comprising 1,10-o-phenanthrolineazosulfonamide derivatives and alkyldithiophosphates
Aly, A. A. M., Awad, I. M. A., El-Mottaleb, M. Abd and El-Aal, K. Abd Complexes of biologically important ligands. I. Ternary complexes of nickel(II) comprising 1,10-o-phenanthrolineazosulfonamide derivatives and alkyldithiophosphates Chemical Papers, Vol.60, No. 2, 2006, 143-148
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Document type:
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Článok z časopisu / Journal Article |
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Collection:
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Chemical papers
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| Author(s) |
Aly, A. A. M.
Awad, I. M. A.
El-Mottaleb, M. Abd
El-Aal, K. Abd
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| Title |
Complexes of biologically important ligands. I. Ternary complexes of nickel(II) comprising 1,10-o-phenanthrolineazosulfonamide derivatives and alkyldithiophosphates
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| Journal name |
Chemical Papers
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| Publication date |
2006
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| Year available |
2006
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| Volume number |
60
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| Issue number |
2
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| ISSN |
0366-6352
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| Start page |
143
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| End page |
148
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| Place of publication |
Poland
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| Publisher |
Versita
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| Collection year |
2006
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| Language |
english
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| Subject |
250000 Chemical Sciences
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| Abstract/Summary |
5-[p-(R-Sulfonyl)phenylazo]-1,10-o-phenanthroline (L) and its octahedral complexes of the type [Ni(R2dtp)2(L)] (where R2dtp = diethyl-or dipropyldithiophosphate) with the core NiN2S4 have been prepared and characterized by spectral, magnetic, and thermogravimetric methods. The thermal decomposition mechanism of the compounds was proposed and the kinetic parameters of decomposition were calculated making use of the Coats—Redfern and Horowitz—Metzger equations.
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