Complexes of biologically important ligands. I. Ternary complexes of nickel(II) comprising 1,10-o-phenanthrolineazosulfonamide derivatives and alkyldithiophosphates

Aly, A. A. M., Awad, I. M. A., El-Mottaleb, M. Abd and El-Aal, K. Abd Complexes of biologically important ligands. I. Ternary complexes of nickel(II) comprising 1,10-o-phenanthrolineazosulfonamide derivatives and alkyldithiophosphates Chemical Papers, Vol.60, No. 2, 2006, 143-148

Document type: Článok z časopisu / Journal Article
Collection: Chemical papers  

Author(s) Aly, A. A. M.
Awad, I. M. A.
El-Mottaleb, M. Abd
El-Aal, K. Abd
Title Complexes of biologically important ligands. I. Ternary complexes of nickel(II) comprising 1,10-o-phenanthrolineazosulfonamide derivatives and alkyldithiophosphates
Journal name Chemical Papers
Publication date 2006
Year available 2006
Volume number 60
Issue number 2
ISSN 0366-6352
Start page 143
End page 148
Place of publication Poland
Publisher Versita
Collection year 2006
Language english
Subject 250000 Chemical Sciences
Abstract/Summary 5-[p-(R-Sulfonyl)phenylazo]-1,10-o-phenanthroline (L) and its octahedral complexes of the type [Ni(R2dtp)2(L)] (where R2dtp = diethyl-or dipropyldithiophosphate) with the core NiN2S4 have been prepared and characterized by spectral, magnetic, and thermogravimetric methods. The thermal decomposition mechanism of the compounds was proposed and the kinetic parameters of decomposition were calculated making use of the Coats—Redfern and Horowitz—Metzger equations.
 
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