Synthesis, Characterization, and Antioxidative Activity of Ternary Rare-Earth Complexes of 5-Fluorouracil-1-acetic Acid and 2,2-Bipyridine

Huang, J., Qu, J. Q., Wang, L. F., Liu, Y. Q., Wang, Y. Y. and Song, Y. M. Synthesis, Characterization, and Antioxidative Activity of Ternary Rare-Earth Complexes of 5-Fluorouracil-1-acetic Acid and 2,2-Bipyridine Chemical Papers, Vol.59, No. 4, 2005, 267-270

Document type: Článok z časopisu / Journal Article
Collection: Chemical papers  
 
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Author(s) Huang, J.
Qu, J. Q.
Wang, L. F.
Liu, Y. Q.
Wang, Y. Y.
Song, Y. M.
Title Synthesis, Characterization, and Antioxidative Activity of Ternary Rare-Earth Complexes of 5-Fluorouracil-1-acetic Acid and 2,2-Bipyridine
Journal name Chemical Papers
Publication date 2005
Year available 2005
Volume number 59
Issue number 4
ISSN 0366-6352
Start page 267
End page 270
Place of publication Poland
Publisher Versita
Collection year 2005
Language english
Subject 250000 Chemical Sciences
250300 Organic Chemistry
Abstract/Summary Seven new solid ternary complexes of 5-fluorouracil-1-acetic acid (HFAA) and 2,2 _ -bipyridine (Bipy) with rare-earth metals have been synthesized. Elemental analysis, molar conductivity, IR, TG-DTA, UV, and 1 H NMR spectra have been used to characterize these complexes. The general formula for the complexes is M(FAA) 3 Bipy · n H 2 O, where M = Y, La, Ce, Sm, Gd, Dy or Er, n = 0, 2 or 5. The antioxidative activity of these complexes was tested. The results obtained showed that the suppression ratios of these complexes for O . − 2 free radical are mostly higher than those of HFAA and Bipy.
 
 
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