Chemistry of Substituted Quinolinones VII. Utility in Syntheses and Reactions of 3-[4-(Chromen-3-ylmethylene)pyrazolin-3-yl]quinolin-2(1H)-ones with Some Bidentate Nucleophiles

Abass, M. and Hassan, A. Chemistry of Substituted Quinolinones VII. Utility in Syntheses and Reactions of 3-[4-(Chromen-3-ylmethylene)pyrazolin-3-yl]quinolin-2(1H)-ones with Some Bidentate Nucleophiles Chemical Papers, Vol.57, No. 4, 2003, 267-277

Document type: Článok z časopisu / Journal Article
Collection: Chemical papers  
 
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Author(s) Abass, M.
Hassan, A.
Title Chemistry of Substituted Quinolinones VII. Utility in Syntheses and Reactions of 3-[4-(Chromen-3-ylmethylene)pyrazolin-3-yl]quinolin-2(1H)-ones with Some Bidentate Nucleophiles
Journal name Chemical Papers
Publication date 2003
Year available 2003
Volume number 57
Issue number 4
ISSN 0366-6352
Start page 267
End page 277
Place of publication Poland
Publisher Versita
Collection year 2003
Language english
Subject 290000 Engineering and Technology
290600 Chemical Engineering
Abstract/Summary Condensation of 3-formylchromenes with pyrazolinylquinolinone afforded the chromenylmethylenepyrazolinones. The reactivity of these products towards different bidentate heteroatom nucleophiles, viz. hydrazine, quinolinylhydrazine, hydroxylamine, ketene-S,S-acetal, sulfanylacetic acid, cyanthioacetamide, thiourea, guanidine, thiobarbituric acid, 2-aminothiophenol, and 4-aminotriazole-3-thiol, was investigated at different mole ratios and reaction conditions. Versatile novel heteropolycyclic systems were obtained as substituents at the 3-pyrazolinylquinolinone moiety derived from nucleophilic ring opening of chromene.
 
 
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