4-Aroylhydrazino-4-thioxo-3-thiabutyrates and their Complexes with Tin(IV)

Huang, G.-S., Zhang, D.-J., Liang, Y.-M., Chen, B.-H. and Ma, Y.-X. 4-Aroylhydrazino-4-thioxo-3-thiabutyrates and their Complexes with Tin(IV) Chemical Papers, Vol.59, No. 3, 2005, 178-181

Document type: ńĆl√°nok z ńćasopisu / Journal Article
Collection: Chemical papers  
 
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Author(s) Huang, G.-S.
Zhang, D.-J.
Liang, Y.-M.
Chen, B.-H.
Ma, Y.-X.
Title 4-Aroylhydrazino-4-thioxo-3-thiabutyrates and their Complexes with Tin(IV)
Journal name Chemical Papers
Publication date 2005
Year available 2005
Volume number 59
Issue number 3
ISSN 0366-6352
Start page 178
End page 181
Place of publication Poland
Publisher Versita
Collection year 2005
Language english
Subject 250000 Chemical Sciences
250300 Organic Chemistry
Abstract/Summary Five new 4-aroylhydrazino-4-thioxo-3-thiabutyrate ligands, synthesized by the reaction of 4- aroylhydrazinodithiocarbamate and chloroacetic ester, and their complexes with tin(IV) have been prepared and characterized by elemental analyses, IR, 1H NMR spectra and molar conductance. It is shown that the O, N, and S atoms of the ligand coordinate to tin to form a chelating dimer and these ligands are tridentate and coordinate to tin(IV) in the enol form in the mole ratio 1 : 1. The central tin atom appears to be six-coordinated.
 
 
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Created: Fri, 08 Jan 2010, 09:57:11 CET by Iveta Drtilov√° . Detailed History