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Solvent Effects on the Aquation of Chlorocobalt(III) Complexes: the Role of Nonlabile Ligand
Grančičová, O. Solvent Effects on the Aquation of Chlorocobalt(III) Complexes: the Role of Nonlabile Ligand Chemical Papers, Vol.59, No. 3, 2005, 149-152
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Document type:
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Článok z časopisu / Journal Article |
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Collection:
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Chemical papers
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| Attached Files |
| Name |
Description |
MIMEType |
Size |
Downloads |
n593a149.pdf
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593a149.pdf |
application/pdf |
152.18KB |
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| Author(s) |
Grančičová, O.
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| Title |
Solvent Effects on the Aquation of Chlorocobalt(III) Complexes: the Role of Nonlabile Ligand
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| Journal name |
Chemical Papers
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| Publication date |
2005
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| Year available |
2005
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| Volume number |
59
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| Issue number |
3
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| ISSN |
0366-6352
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| Start page |
149
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| End page |
152
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| Place of publication |
Poland
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| Publisher |
Versita
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| Collection year |
2005
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| Language |
english
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| Subject |
250000 Chemical Sciences
250100 Physical Chemistry (incl. Structural)
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| Abstract/Summary |
The aquation of trans-[Co(me2tn)2Cl2]+, β-cis-[Co(trien)Cl2]+, and trans-[Co(2,2,3-tet)Cl2 ]+ has been investigated in aqueous mixtures of methanol, tert-butanol, acetonitrile, dimethyl sulfoxide, sulfolane, N-methyl-2-pyrrolidinone, ethylene carbonate, and urea, respectively, at 298.1 K. Results are discussed in terms of the importance of structure of aqueous binary mixtures in preferential solvation of complex ions and of size and hydrophobicity of the nonlabile ligands.
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