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Influence of Solvent on the Epoxidation of Allyl Alcohol by Hydrogen Peroxide over Titanium Silicalite Catalysts
Wróblewska, A., Rzepkowska, M., Lenart, S., Westerlich, S., Grzmil, B. and Milchert, E. Influence of Solvent on the Epoxidation of Allyl Alcohol by Hydrogen Peroxide over Titanium Silicalite Catalysts Chemical Papers, Vol.59, No. 2, 2005, 139-142
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Document type:
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Článok z časopisu / Journal Article |
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Collection:
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Chemical papers
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| Attached Files |
| Name |
Description |
MIMEType |
Size |
Downloads |
n592a139.pdf
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592a139.pdf |
application/pdf |
347.00KB |
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| Author(s) |
Wróblewska, A.
Rzepkowska, M.
Lenart, S.
Westerlich, S.
Grzmil, B.
Milchert, E.
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| Title |
Influence of Solvent on the Epoxidation of Allyl Alcohol by Hydrogen Peroxide over Titanium Silicalite Catalysts
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| Journal name |
Chemical Papers
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| Publication date |
2005
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| Year available |
2005
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| Volume number |
59
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| Issue number |
2
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| ISSN |
0366-6352
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| Start page |
139
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| End page |
142
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| Place of publication |
Poland
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| Publisher |
Versita
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| Collection year |
2005
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| Language |
english
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| Subject |
250000 Chemical Sciences
250300 Organic Chemistry
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| Abstract/Summary |
The epoxidation of allyl alcohol by 30 mass % hydrogen peroxide over titanium silicalite catalysts in the environment of protic and aprotic solvents has been investigated. The influence of the titanium silicalite catalysts TS-1, TS-2, and Ti-Beta and a protic solvent (methanol) and aprotic solvents (acetonitrile and methyl ethyl ketone) on the allyl alcohol epoxidation was studied. The catalyst solvent system, namely TS-2–methanol, allowing to achieve glycidol with the highest selectivity has been determined.
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