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Epoxidation of Methallyl Chloride with a 30 % H202 over the TS-1 Catalyst
Rzepkowska, M., Wróblewska, A. A. and Lewandowski, G. Epoxidation of Methallyl Chloride with a 30 % H202 over the TS-1 Catalyst Chemical Papers, Vol.58, No. 5, 2004, 324-329
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Document type:
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Článok z časopisu / Journal Article |
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Collection:
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Chemical papers
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| Attached Files |
| Name |
Description |
MIMEType |
Size |
Downloads |
n585a324.pdf
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585a324.pdf |
application/pdf |
160.43KB |
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| Author(s) |
Rzepkowska, M.
Wróblewska, A. A.
Lewandowski, G.
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| Title |
Epoxidation of Methallyl Chloride with a 30 % H202 over the TS-1 Catalyst
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| Journal name |
Chemical Papers
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| Publication date |
2004
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| Year available |
2004
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| Volume number |
58
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| Issue number |
5
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| ISSN |
0366-6352
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| Start page |
324
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| End page |
329
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| Place of publication |
Poland
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| Publisher |
Versita
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| Collection year |
2004
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| Language |
english
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| Subject |
250000 Chemical Sciences
250300 Organic Chemistry
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| Abstract/Summary |
The process of epoxidation of methallyl chloride to β-methylepichlorohydrin was carried out with a 30 % hydrogen peroxide in the presence of the titanium silicalite catalyst TS-1. The process was carried out in an autoclave or in a glass reactor at atmospheric pressure. The optimum technological parameters (temperature 20°C, mole ratio n(MAC)/n(H2O2) 1:1, methanol content 40 mass %, TS- 1 content 1.0—2.0 mass %, reaction time 120 min) were determined so that the applied epoxidation system allowed obtaining β-methylepichlorohydrin with a good selectivity (93—94 mole %) and high conversion of hydrogen peroxide (95—99 mole %).
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