Epoxidation of Methallyl Chloride with a 30 % H202 over the TS-1 Catalyst

Rzepkowska, M., Wróblewska, A. A. and Lewandowski, G. Epoxidation of Methallyl Chloride with a 30 % H202 over the TS-1 Catalyst Chemical Papers, Vol.58, No. 5, 2004, 324-329

Document type: Článok z časopisu / Journal Article
Collection: Chemical papers  
 
Attached Files
Name Description MIMEType Size Downloads
n585a324.pdf 585a324.pdf application/pdf 160.43KB 0

Author(s) Rzepkowska, M.
Wróblewska, A. A.
Lewandowski, G.
Title Epoxidation of Methallyl Chloride with a 30 % H202 over the TS-1 Catalyst
Journal name Chemical Papers
Publication date 2004
Year available 2004
Volume number 58
Issue number 5
ISSN 0366-6352
Start page 324
End page 329
Place of publication Poland
Publisher Versita
Collection year 2004
Language english
Subject 250000 Chemical Sciences
250300 Organic Chemistry
Abstract/Summary The process of epoxidation of methallyl chloride to β-methylepichlorohydrin was carried out with a 30 % hydrogen peroxide in the presence of the titanium silicalite catalyst TS-1. The process was carried out in an autoclave or in a glass reactor at atmospheric pressure. The optimum technological parameters (temperature 20°C, mole ratio n(MAC)/n(H2O2) 1:1, methanol content 40 mass %, TS- 1 content 1.0—2.0 mass %, reaction time 120 min) were determined so that the applied epoxidation system allowed obtaining β-methylepichlorohydrin with a good selectivity (93—94 mole %) and high conversion of hydrogen peroxide (95—99 mole %).
 
 
User Comments
 
Access Statistics: 0 Abstract Views, 0 File Downloads Detailed Statistics
Created: Mon, 04 Jan 2010, 13:26:58 CET by Iveta Drtilová . Detailed History