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Macromolecule—Palladium Complexes as Catalysts for the Synthesis of Hydrogen Peroxide
Biffis, A. and Králik, M. Macromolecule—Palladium Complexes as Catalysts for the Synthesis of Hydrogen Peroxide Chemical Papers, Vol.56, No. 3, 2002, 178-181
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Document type:
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Článok z časopisu / Journal Article |
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Collection:
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Chemical papers
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| Attached Files |
| Name |
Description |
MIMEType |
Size |
Downloads |
n563a178.pdf
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563a178.pdf |
application/pdf |
108.62KB |
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| Author(s) |
Biffis, A.
Králik, M.
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| Title |
Macromolecule—Palladium Complexes as Catalysts for the Synthesis of Hydrogen Peroxide
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| Journal name |
Chemical Papers
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| Publication date |
2002
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| Year available |
2002
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| Volume number |
56
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| Issue number |
3
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| ISSN |
0366-6352
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| Start page |
178
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| End page |
181
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| Place of publication |
Poland
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| Publisher |
Versita
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| Collection year |
2002
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| Language |
english
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| Subject |
250000 Chemical Sciences
250500 Macromolecular Chemistry
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| Abstract/Summary |
Commercial resin supports containing aromatic nitrogen bases as functional groups have been used as macromolecular ligands for palladium(II), thus yielding insoluble macromolecule—metal complexes. Preliminary tests were run with these materials as catalysts for the preparation of hydrogen peroxide from carbon monoxide, oxygen, and water. Pretreatment of the catalyst with an organic solvent was found to be necessary in order to achieve catalytic activity. The best results (turnover number = 6) were obtained with pretreatment in dioxane.
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