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Effect of Ultrasound on One-Pot Conversion of Alcohols to Nitro and Azido Compounds
Mečiarová, M., Toma, Š. and Babiak, P. Effect of Ultrasound on One-Pot Conversion of Alcohols to Nitro and Azido Compounds Chemical Papers, Vol.58, No. 2, 2004, 104-108
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Document type:
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Článok z časopisu / Journal Article |
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Collection:
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Chemical papers
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| Attached Files |
| Name |
Description |
MIMEType |
Size |
Downloads |
n582a104.pdf
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582a104.pdf |
application/pdf |
124.27KB |
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| Author(s) |
Mečiarová, M.
Toma, Š.
Babiak, P.
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| Title |
Effect of Ultrasound on One-Pot Conversion of Alcohols to Nitro and Azido Compounds
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| Journal name |
Chemical Papers
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| Publication date |
2004
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| Year available |
2004
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| Volume number |
58
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| Issue number |
2
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| ISSN |
0366-6352
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| Start page |
104
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| End page |
108
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| Place of publication |
Poland
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| Publisher |
Versita
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| Collection year |
2004
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| Language |
english
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| Subject |
250000 Chemical Sciences
250300 Organic Chemistry
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| Abstract/Summary |
Synthesis of aliphatic nitro and azido compounds from corresponding alcohols under ultrasonic irradiation was studied. Ultrasonic irradiation of the reaction mixture ROH/NaNO2/HCl allowed to shorten the reaction time and increase yields of aliphatic nitro compounds. Ultrasonic irradiation of the reaction mixture PhCH2OH/NaN3/PPh3 resulted in formation of PhCH2N3 in yields comparable with those of the silent experiments. The next product was benzyl chloride and not benzylamine as was described in the literature.
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