Effect of Polymer on Structural Characteristics and Steel Corrosion of Cement-Poor Mortar

Janotka, I. and Krajči, Ľ. Effect of Polymer on Structural Characteristics and Steel Corrosion of Cement-Poor Mortar Chemical Papers, Vol.58, No. 2, 2004, -

Document type: Článok z časopisu / Journal Article
Collection: Chemical papers  
 
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Author(s) Janotka, I.
Krajči, Ľ.
Title Effect of Polymer on Structural Characteristics and Steel Corrosion of Cement-Poor Mortar
Journal name Chemical Papers
Publication date 2004
Year available 2004
Volume number 58
Issue number 2
ISSN 0366-6352
Place of publication Poland
Publisher Versita
Collection year 2004
Language english
Subject 250000 Chemical Sciences
250500 Macromolecular Chemistry
Abstract/Summary Results of the study of styrene—acrylate dispersion influence on mechanical properties, hydrate phase, and pore structure formation as well as steel corrosion development in Portland cement mortar are discussed. Mortars with low cement content are used for the tests instead of usually studied mortars of cement-rich content. The object of interest was to ascertain the effect of polymer addition on cement-poor mortar behaviour using unfavourable mortar mixture composition and bad conditions for cement hydration. The specimens were exposed to 240-day dry (60 % R.H.) and wet (95 % R.H.) air cure at 20°C. Polymer increases absorption capacity, capillarity, total pore volume, and porosity of the mortar relative to that without styrene—acrylate dispersion. Dynamic modulus of elasticity and compressive strength are declined. The main reason of this lies in lower bulky mass of hydrate phase and higher cumulative volume of pores in polymer-modified cement mortar (PMCM) compared to those found in control cement mortar (CCM). Air voids occur in PMCM instead of bulky cementitious material due to foaming effect of polymer. Its addition decreases alkalinity of cement mortar and increases the permeability, making the pore structure coarser than that formed in CCM. The capability of moist air transport through the bulk of mortars determines the corrosion rate of steel. Steel corrosion characteristics are evaluated by three independent methods indicating a close connection between the developed pore structure and the corrosion rate of steel in the mortars.
 
 
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